Crystallization Processes under Hydrothermal Conditions PDF

Edited by A. N. Lobachev

Part of the Studies in Soviet Science series

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Description

This collection conta ins the results of a number of investiga- tions which have been carried out in the Hydrothermal Synthesis Laboratory of the Institute of Crystallography, Academy of Sciences of the USSR; it constitutes a continuation of an earlier collection which appeared in 1968: Hydrothermal Synthesis of Crystals.

Problems associated with the synthesis of oxides, simple and complex sulfides, carbonates, silicates, and germanates are consid- ered, and a great deal of factual material relating to the growth of single crystals of some of these compounds on a seed is presented.

Some of the articles pay special attention to the kinetic asp- ect of the growth of crystals; the conditions of growth are relat- ed to the morphological characteristics of the growing faces, and the relationship between the habit of the crystals and the oomposi- tion and constitution of the solutions is considered.

A fair number of articles are concerned with the crystalliza- tion of new compounds, most of which have now been synthesized under hydrothermal conditions for the very first time; these in- clude ternary chalcohalides of composition AVBvIVVII. zirconates, lithium silicates, and germanates. The collection also contains a description of the apparatus used for precision measurements at high temperatures and pres- sures.

We hope that this publication will present a better idea of the special characteristics of the hydrothermal method of synthes- izing and .growing crystals, and will prove useful to all those in- terested in this field of knowledge.