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Emerging Technologies in Hazardous Waste Management 7, Hardback Book

Emerging Technologies in Hazardous Waste Management 7 Hardback

Edited by D. William Tedder, Frederick G. Pohland

Hardback

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TheI&ECSYMPOSIUMfromwhichthisvolumewasderivedfeatured519presen- tationsat88technicalsessionsduringathree-daymeetingonSeptember17-20, 1996in Birmingham,Alabamawith580registrants.

Thefinalselectionsforthechaptersincluded hereinwerebasedonpeerreview,scientificmerit,theeditors'perceptionsoflastingvalue orinnovativefeatures, andthegeneralapplicabilityofeitherthetechnologyitselforthe scientificmethodsandscholarlydetailsprovidedbytheauthors.

Thevolume isacontinuationofathemeinitiatedin 1990. Itspredecessors,Emerg- ing Technologies in Hazardous Waste Management, ACS Symposium Series No. 422 (1990), EmergingTechnologiesinHazardous WasteManagementII,ACSSymposiumSe- ries No. 468 (1991), Emerging Technologies in Hazardous WasteManagement III, ACS SymposiumSeriesNo. 518(1993), EmergingTechnologiesinHazardous WasteManage- mentIV, ACSSymposium Series No. 554 (1994),Emerging Technologies in Hazardous WasteManagement V.

ACSSymposiumSeriesNo. 607(1995), andEmergingTechnolo- gies in Hazardous Waste Management VI, American AcademyofEnvironmental Engi- neersPublication (1996), arerelatedcontributionsonhazardouswastemanagement,but eachvolumeisessentiallydifferent. Byinspection,thereadermayquicklyrecognizethis diversity,andalsoconcludethatnosinglevolumecandojusticetothebreadthanddepth oftechnologiesbeingdevelopedandappliedinpractice.

Thecontributionspresented in thisvolumearedivided intofourseparatebutcom- plementary sections, including: (1) Chemical and Thermal Treatment; (2) Biochemical Treatment;(3)SeparationTechnologies;and(4)RadioactiveWasteTreatment.

D. WilliamTedder FrederickG. Pohland GeorgiaInstituteofTechnology UniversityofPittsburgh Atlanta, Georgia30332-0100 Pittsburgh,Pennsylvania15261-2294 v ACKNOWLEDGMENTS The Industrial & Engineering Chemistry (I&EC) Division ofACS organized and sponsored the symposium.

ACS Corporate Associates was a majorfinancial cosponsor; theAmericanInstituteofChemicalEngineers(AIChE)EnvironmentalSciencesDivision, theAIChECenterforWasteReductionTechnologies,theAmericanAcademyofEnviron- mental Engineers,andtheJointAssociationfor theAdvancementsofSupercriticalFluid Technologywerenominalcosponsors;andEnviroExpocositedanexhibition.

Thisgener- osity was essential to the overall successofthe symposium and is gratefully acknow- ledged. vii CONTENTS I. EmergingTechnologiesinHazardousWasteManagementVII:AnOverview...FrederickG. PohlandandD. WilliamTedder ChemicalandThermalMethods 2. GranularIronOxideasaCatalystinChemicalOxidationofOrganic Contaminants...9 MiratD.

Gurol,Shu-SungLin,andNileshBhat 3. AnElectronBeamGeneratedPlasmaReactorforDecompositionof HalogenatedVOCs 23 S.

A. Vitale, K. Hadidi,D. R. Cohn, L. Bromberg,andP. Falkos 4. IncinerationandThermalTreatmentofChemicalAgentsandChemicalWeapons 33 F.

C. GouldinandE. M. Fisher 5. PredictingStabilityConstantsofVariousChelatingAgentsUsingQSAR Technology 49 R.

W. Okey,S. Lin,andP. K. A. Hong 6. MineralizationofHazardousChemicalsbyHemeReaction ...69 GuyoungKang,JimoJung,KapsongPark,andDavidK.

Stevens BiochemicalTreatment 7. AnaerobicTransformationsofCarbonTetrachloride:CombinedBacterialand AbioticProcesses 81 FlynnW.

Picardal,SanggooKim,AnnaRadue,andDeberaBackhus 8. BiorecoveryofMetalsfromAcidMineDrainage...91 RakeshGovind,UmaKumar,RamaPuligadda,JimmyAntia,and HenryTabak ix x Contents 9.

BiotreatmentofMinewater-ContainingCyanidesbyUsingImmobilizedCell Technology 103 Onguri K.

Vijaya,G. R. V. Babu,JackAdams,JamesH. Wolfram,and KiritD. Chapatwala 10. Augmentationofin-SituSubsoilRemediationUsingColloidalGasDispersions 113 P.

G. Chaphalkar,K. T. Valsaraj,D. Roy, W. D. Constant,andP. Lee 11. EffectofSorptionontheMicrobialReductiveDechlorinationofSoil-Bound Chloroalkenes 127 SpyrosG.

PavlostathisandPingZhuang SeparationTechnologies 12.

TheRemovalofVOCsfromExhaustAirandVapourCondensatesby MembraneProcesses ...

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